Jul 3, 2010 09:32
13 yrs ago
Russian term
координационный узел
Russian to English
Other
Chemistry; Chem Sci/Eng
полимеры
строение координационного узла в хелатных полимерах
Proposed translations
(English)
4 -1 | coordination junction | Michael Kislov |
4 +1 | coordination node | Natalie |
3 | coordinate (semipolar) cross-link | Alexander Ryshow |
3 | linker | rns |
Proposed translations
-1
1 hr
Selected
coordination junction
The high developedperiphery of coordination compound's molecule shields its coordination junction by reducing both elec-trostatic (charge, dipole, etc.) and nonvalence (Van der Waals forces, hydrogen bonds, etc.) componentsof intramolecular interaction [3, 41.
http://www.pdfqueen.com/html/aHR0cDovL2hhbC5hcmNoaXZlcy1vdXZ...
http://www.pdfqueen.com/html/aHR0cDovL2hhbC5hcmNoaXZlcy1vdXZ...
Peer comment(s):
disagree |
Natalie
: Это выражение употребляется исключительно в переводных статьях - в основном с русского
2 days 8 hrs
|
4 KudoZ points awarded for this answer.
8 mins
coordinate (semipolar) cross-link
Iron Tris(bipyridine) PEG Hydrogels with Covalent and Metal ...
- [ Перевести эту страницу ]
9 Dec 2008 ... (35) Hydrogels with metal coordinate cross-links have also been reported.(36-39) For instance, the combination of lanthanide metals and PEG ...
pubs.acs.org/doi/abs/10.1021/bm800998g
или coordinate (semipolar) nodule
Improvement strategies of leguminosae biotechnology - Результат из Google Книги
Pawan K. Jaiwal, Rana P. Singh - 2003 - Science - Страниц: 411
Late responses: Root cortical cell divisions and nodule formation The ... coordinate nodule formation. It apears that rhizobia convert the process of ...
books.google.com.by/books?isbn=1402014058...
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Note added at 9 мин (2010-07-03 09:42:07 GMT)
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http://www.multitran.ru/c/m.exe?&s=����&l1=2&l2=1
- [ Перевести эту страницу ]
9 Dec 2008 ... (35) Hydrogels with metal coordinate cross-links have also been reported.(36-39) For instance, the combination of lanthanide metals and PEG ...
pubs.acs.org/doi/abs/10.1021/bm800998g
или coordinate (semipolar) nodule
Improvement strategies of leguminosae biotechnology - Результат из Google Книги
Pawan K. Jaiwal, Rana P. Singh - 2003 - Science - Страниц: 411
Late responses: Root cortical cell divisions and nodule formation The ... coordinate nodule formation. It apears that rhizobia convert the process of ...
books.google.com.by/books?isbn=1402014058...
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Note added at 9 мин (2010-07-03 09:42:07 GMT)
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http://www.multitran.ru/c/m.exe?&s=����&l1=2&l2=1
Peer comment(s):
neutral |
Natalie
: В первой ссылке говорится о формировании координационных связей, а вторая вообще из области ботаники
47 mins
|
+1
54 mins
coordination node
The tetrahedral structure of the coordination node is not characteristic for nickel chelates with 8-amino vinyl ketones [1, 2} at least in the solid phase, ...
http://www.springerlink.com/index/RV0830K035G42248.pdf
possible using immobilized nickel chelates. The nickel chelates of the polymeric ligands PE-g-PSSA (coordination node NiO6) and PE-g-PEAK ...
http://www.springerlink.com/index/W750W234008300H8.pdf
The major differences in the molecular structure of 1a and 1 concern: a) the planarity of the chelate cycles and coordination node, and b) the torsion ...
http://www3.interscience.wiley.com/journal/114206251/article...
Другие линки:
http://tinyurl.com/37tol35
http://www.springerlink.com/index/RV0830K035G42248.pdf
possible using immobilized nickel chelates. The nickel chelates of the polymeric ligands PE-g-PSSA (coordination node NiO6) and PE-g-PEAK ...
http://www.springerlink.com/index/W750W234008300H8.pdf
The major differences in the molecular structure of 1a and 1 concern: a) the planarity of the chelate cycles and coordination node, and b) the torsion ...
http://www3.interscience.wiley.com/journal/114206251/article...
Другие линки:
http://tinyurl.com/37tol35
19 mins
linker
хелатные полимеры — coordination polymers
Coordination
The crystal structure and dimensionality of the coordination polymer is determined by the functionality of the linker and the coordination geometry of the metal center. Dimensionality is generally driven by the metal center which can have the ability to bond to as 16 functional sites on linkers. This number of possible bonds is the coordination number. Coordination numbers are more often between 2 and 10, and the bonding sites are separated by distinct angles. Coordination numbers are shown in planer geometry in Figure 2. In Figure 1 the 1D structure is 2-coordinated, the planer is 4-coordinated, and the 3D is 8-coordinated. Figure 3 shows structures hinting at the complexity that is possible by changing coordination geometry.
http://en.wikipedia.org/wiki/Coordination_polymers#Coordinat...
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Note added at 25 mins (2010-07-03 09:58:36 GMT)
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coordination site is also an option, albeit less probable — http://tinyurl.com/327p2nu — because хелатные полимеры is translated as chelate polymers much less frequently.
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Note added at 55 mins (2010-07-03 10:28:06 GMT)
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хелатные полимеры = КООРДИНАЦИОННЫЕ ПОЛИМЕРЫ, но в английском чаще говорят о последних.
КООРДИНАЦИОННЫЕ ПОЛИМЕРЫ (внутрикомплексные полимеры, хелатные полимеры, клешневидные полимеры), высокомол. соед., основная цепь к-рых построена из хелатных колец (см. Координационные соединения, Хелаты), Чаще всего координационные полимеры образуют катионы переходных металлов, хотя известны координационные полимеры металлов почти всех групп (кроме пятой) периодич. системы. Небольшие размеры катионов переходных металлов в сочетании с большим эффективным зарядом, а также наличие в ряде случаев незаполненных d-орбиталей обеспечивают довольно прочную связь металла с донорными группами лиганда. По строению осн. цепи различают координационные полимеры с основными неорг. цепями (ф-лы I) и элементоорг. цепями (II). — http://www.xumuk.ru/encyklopedia/2121.html
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Note added at 1 hr (2010-07-03 10:33:26 GMT)
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Because (1) they don't like borrowed words in the English language and (2) they like to name things by what actually defines them (in this case, coordination) rather than the attribute (in this case, multiple bonds to the same metal (which is called chelation).
http://en.wikipedia.org/wiki/Coordination_polymers
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Note added at 1 hr (2010-07-03 10:37:58 GMT)
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Note to (1) — appearances to the contrary notwithstanding. :)
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Note added at 1 hr (2010-07-03 10:40:56 GMT)
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Google Scholar (научные статьи и патенты) links — http://tinyurl.com/34wdjba
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Note added at 1 day4 hrs (2010-07-04 13:41:06 GMT)
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==========================================
coordination site news seems to be a better translation because the text, as it turned out, also contains 'координационная сфера' — http://tinyurl.com/39jdwxg — which cannot be translated by using linker
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Coordination
The crystal structure and dimensionality of the coordination polymer is determined by the functionality of the linker and the coordination geometry of the metal center. Dimensionality is generally driven by the metal center which can have the ability to bond to as 16 functional sites on linkers. This number of possible bonds is the coordination number. Coordination numbers are more often between 2 and 10, and the bonding sites are separated by distinct angles. Coordination numbers are shown in planer geometry in Figure 2. In Figure 1 the 1D structure is 2-coordinated, the planer is 4-coordinated, and the 3D is 8-coordinated. Figure 3 shows structures hinting at the complexity that is possible by changing coordination geometry.
http://en.wikipedia.org/wiki/Coordination_polymers#Coordinat...
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Note added at 25 mins (2010-07-03 09:58:36 GMT)
--------------------------------------------------
coordination site is also an option, albeit less probable — http://tinyurl.com/327p2nu — because хелатные полимеры is translated as chelate polymers much less frequently.
--------------------------------------------------
Note added at 55 mins (2010-07-03 10:28:06 GMT)
--------------------------------------------------
хелатные полимеры = КООРДИНАЦИОННЫЕ ПОЛИМЕРЫ, но в английском чаще говорят о последних.
КООРДИНАЦИОННЫЕ ПОЛИМЕРЫ (внутрикомплексные полимеры, хелатные полимеры, клешневидные полимеры), высокомол. соед., основная цепь к-рых построена из хелатных колец (см. Координационные соединения, Хелаты), Чаще всего координационные полимеры образуют катионы переходных металлов, хотя известны координационные полимеры металлов почти всех групп (кроме пятой) периодич. системы. Небольшие размеры катионов переходных металлов в сочетании с большим эффективным зарядом, а также наличие в ряде случаев незаполненных d-орбиталей обеспечивают довольно прочную связь металла с донорными группами лиганда. По строению осн. цепи различают координационные полимеры с основными неорг. цепями (ф-лы I) и элементоорг. цепями (II). — http://www.xumuk.ru/encyklopedia/2121.html
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Note added at 1 hr (2010-07-03 10:33:26 GMT)
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Because (1) they don't like borrowed words in the English language and (2) they like to name things by what actually defines them (in this case, coordination) rather than the attribute (in this case, multiple bonds to the same metal (which is called chelation).
http://en.wikipedia.org/wiki/Coordination_polymers
--------------------------------------------------
Note added at 1 hr (2010-07-03 10:37:58 GMT)
--------------------------------------------------
Note to (1) — appearances to the contrary notwithstanding. :)
--------------------------------------------------
Note added at 1 hr (2010-07-03 10:40:56 GMT)
--------------------------------------------------
Google Scholar (научные статьи и патенты) links — http://tinyurl.com/34wdjba
--------------------------------------------------
Note added at 1 day4 hrs (2010-07-04 13:41:06 GMT)
--------------------------------------------------
==========================================
coordination site news seems to be a better translation because the text, as it turned out, also contains 'координационная сфера' — http://tinyurl.com/39jdwxg — which cannot be translated by using linker
==========================================
Note from asker:
почему coordination polymers а не chelate polymers? |
sorry, why "coordination polymers" but not "chelate polymers"? |
Discussion